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Breathe Magazine requested for me to rewrite my original “Something Fishy” article for their Hunter Valley Wine Show edition.

Something fishy… What’s the Story of Fish in Wine?

I often get asked why there are warnings on wine labels pertaining to fish, milk and egg products. Aren’t the basic ingredients of wine just grapes and yeast? Sometimes we need a little help to optimise our basic ingredients.

In the Fermentation process, yeast converts the grape sugars (glucose and fructose) into alcohol (and carbon dioxide). Yeast can be found naturally on the skins of the grapes, or it can be introduced. The type of yeast can also affect the flavour, aroma, texture and body of the final wine.

The winemaker may also choose to put the wine through secondary fermentation. Malolactic Fermentation (or Malo for short – pronounced “May-Low”) would usually occur after the primary ferment. During Malo, Lactic Acid Bacteria get busy converting Malic acid from the grapes into Lactic acid in the wine. Lactic acid is not as sharp and acidic to taste, resulting in a wine that has a smoother mouth feel. Malo can result in a buttery, creamy Chardonnay, but if not done skilfully can end up causing faults in the wine.

It is a sad ending for the yeast as after primary ferment, it dies. Unfortunately, the yeast is a casualty of our consumption. Making matters worse, all the residual and dead yeast cells or “lees” are now floating around in our wine. There may also be natural proteins, bacteria and other particles suspended in the wine. I don’t like “floaties” in my Shiraz or Chardonnay. What is the solution to this problem?

Winemakers use a fining agent to flocculate at various stages during wine production, ensuring your Hunter Valley Semillon is crystal clear. Clarity, brightness and transparency are important for both the wine judge, and us wine drinkers.

Flocculation: [verb] forced removal of sediment from a liquid through addition of a flocculating agent. Gravity controlled flocculation precipitates solids within a liquid.

Now for the science lesson: as the diagram suggests, the fining agent is added to the top of the tank, weighs down on the dead yeast cells (and other “floaties”) and drags everything to the bottom of the tank where it can be siphoned off.

Fining agents can improve haze, phenolics, astringency, colour, flavour and even off-odour in wine. Therefore, fining is a process which results in a wine created with finesse, which may also have attractive qualities not present in unfined wine.

Stabilisation can be used to prevent wine faults caused by environmental changes to temperature, humidity and movement. Unstable wines can be subject to haze, tartrates and premature ageing. For example, Cold stabilisation encourages liquid tartaric acid to solidify. “Wine Diamonds” (tartrate crystals) form when the wine is very cold. They develop in small crystals or long shards and can be removed prior to bottling. Sometimes these form in the finished bottle – they may look like glass but are completely harmless.

So where does fish come into this? Not to worry – winemakers are certainly not throwing seafood medley into the tank!

Below are some common fining agents:

Isinglass (pronounced eye-sin-glass) is a gelatin derived from the air bladder of a fish – especially and traditionally the sturgeon. Isinglass is expensive, delicate, will not strip flavour and often used with white wines.

Gelatin has been used to fine wine since Roman civilisation. It can remove harsh tannins, bitter flavours, and improve astringency.

Casein. Casein is an active protein in skim milk or powdered skim milk. It can be used to nullify astringency and bitterness in white wines, sometimes lightening the colour.

PVPP or polyvinyl-polypyrrolidone is a synthetic polymer chain that behaves like a natural protein.

Albumin is the fining agent relating to eggs. Only the whites are used (sometimes powdered) – so never sunny side up! This is usually reserved for red wines and believe it or not it’s only 1-2 egg whites for 100 Litres of wine.

There are natural proteins present in grapes that may cause a cloudy haze if the wine is subject to higher temperatures. Bentonite is a naturally occurring clay or mineral derivative that stabilises the wine, preventing cloudy protein haze in the wine.

Did you know? Bulls blood was commonly used as a fining agent in many European countries including France, until 1997 when the EU banned this practice as a measure to curb Mad Cow’s Disease.

If I’m allergic to seafood do I have to avoid wine?

No. Not even with wines fined with Isinglass. The protein in fish which commonly causes allergic reactions is called parvalbumin. It’s not normally found in isinglass.

Modern manufacture of isinglass ensures no residual parvalbumin remains. The European Food Safety Commission led the way and granted isinglass exemption from allergen labelling laws. In 2009, Food Standards Australia New Zealand (FSANZ) also granted food labelling exemption for isinglass in beer and wine. Even if trace parvalbumin snuck into the wine with the isinglass, it would settle with the isinglass when flocculated and be removed in the filtration process.

This doesn’t sound kosher!

Well technically, isinglass that is derived from a sturgeon isn’t. However isinglass from a kosher fish is. Other un-kosher fining agents include gelatin, casein.

I’m a vegetarian /vegan?

A lot of wines on the market are still unfined or use vegetarian-friendly fining agents. Synthetic fining agents are increasingly popular, and Bentonite is one of the most common fining agents. It is important to consider that some wines and many beers may not be suitable.

Vegans can look for wines that boast “unfined” or “unfiltered” or Bentontite/clay. Some wineries are cleverly labelling for vegetarian and vegan consumption determined by their winemaking processes. Just because some wines are labelled as vegetarian-friendly doesn’t mean that the wines that don’t specify aren’t already suitable for vegetarians or vegans. Continue enjoying Hunter Valley wines and if you are concerned – read the label and ask the friendly folks at the winery.

Testing has shown that there is limited capacity for wines to absorb fining agents and when they have been detected, only in negligent proportions. Fining is considered more natural and delicate a process than filtration which can rapidly strip a wine of colour and flavour. It’s also an important part of traditional winemaking practice that Australian winemakers have inherited from our old world wine countries.

So now you know more about the processes behind some of our proud award winning wines– celebrate quality Hunter Valley wines and appreciate the complexity of the science and skill it took to produce them.

Cheers to that!

 

This article was published in Breathe Magazine – Issue 30, Spring 2011  “Hunter Valley Wine Show edition” – see link.

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Some people don’t correlate the relationship between sugar, yeast and alcohol.

In Australia the only legal permissable use of cane sugar in wine is for “dosage” in Methode Champenoise or Sparkling Wines. (This is one reason Sparkling Wines have more calories ladies…). Thus, the only legal way (in Australia) to get sugar in your fruit (grapes) is to make sure they ripen – natural sugars are glucose and fructose.

We are allowed to add alternate means of acid and tannin as well as preservative. This is a good thing:

Consider some other kind of fruit growing in your back yard. If you picked a tomato when it was green, there is a higher amount of acid than there is sugar. The longer you leave it on the vine, the more this balance sways the opposite way – less acid to higher sugar.

Same thing goes for grape vines, we need more sugar in our grapes than acid for the average wine. Keeping in mind this is natural sugars that build up through photosynthesis in the grape vine. (Sunlight + leaves = ripe fruit)  But if we harvest too ripe, we can then back up the balance with extra acid/ tannin. If we harvest too early its going to taste tart and acidic and will probably have to be used for Sparkling Wines.

Why is all this important? What I am about to demonstrate is a science lesson.

In order to make wine, we use the basic principal called fermentation. Fermentation works like this:

Sugar +Yeast = Carbon dioxide + Alcohol

Yeast can naturally be found on the skin of the grape, so traditionally none needs to be added. However, as later described, “super” yeasts have been grown in order to be more resistant as well as consistent. Yeast will also affect the flavour.

Yeast is a living thing. Consider this: “Yeast Man”

“Yeast Man” eats sugar, and through this process, Alcohol and Carbon Dioxide are released. This is why wine is alcoholic, and also why Champagne has bubbles. (More on this another day).

But “Yeast Man’s” Kryptonite is: eating and shitting in the same place. Hes a greedy little bugger and creates a sort of toxicity that even he can’t survive. Yeasts will keep going through this fermentation process until:

  1. He runs out of sugar
  2. The temperature gets too high and he dies
  3. The temperature gets too low and he goes to sleep
  4. Too much alcohol takes over in the early stages of the wine and he drowns in his own piss

The amount of sugar in the fruit will depend on the amount of alcohol in the wine – unless the yeast is killed and residual sugar is left over. This often produces a fruity or sweet wine.

Some yeasts are more resistant than others but on the most part – too much alcohol or the wrong temperature will kill a normal yeast. This is when “Yeast Man” gets a makeover and they reinvent him as a da da da da…. SUPER YEAST MAN!

Super Yeast Man laughs in the face of danger. (Well not really, but they can build yeasts that don’t die so easily).

But it has not been identified whether Super Yeast Man’s Clark Kent is named Brett (after Brettanomyces) or Lee (as Lees is the name given to dead yeast cells).

So now you understand (or are even more confused than before) about Yeast and Fermentation, take a moment to consider all the living yeast cells that had to die for your glass of wine. Casualties of consumption.

Cheers!

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