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Breathe Magazine requested for me to rewrite my original “Something Fishy” article for their Hunter Valley Wine Show edition.

Something fishy… What’s the Story of Fish in Wine?

I often get asked why there are warnings on wine labels pertaining to fish, milk and egg products. Aren’t the basic ingredients of wine just grapes and yeast? Sometimes we need a little help to optimise our basic ingredients.

In the Fermentation process, yeast converts the grape sugars (glucose and fructose) into alcohol (and carbon dioxide). Yeast can be found naturally on the skins of the grapes, or it can be introduced. The type of yeast can also affect the flavour, aroma, texture and body of the final wine.

The winemaker may also choose to put the wine through secondary fermentation. Malolactic Fermentation (or Malo for short – pronounced “May-Low”) would usually occur after the primary ferment. During Malo, Lactic Acid Bacteria get busy converting Malic acid from the grapes into Lactic acid in the wine. Lactic acid is not as sharp and acidic to taste, resulting in a wine that has a smoother mouth feel. Malo can result in a buttery, creamy Chardonnay, but if not done skilfully can end up causing faults in the wine.

It is a sad ending for the yeast as after primary ferment, it dies. Unfortunately, the yeast is a casualty of our consumption. Making matters worse, all the residual and dead yeast cells or “lees” are now floating around in our wine. There may also be natural proteins, bacteria and other particles suspended in the wine. I don’t like “floaties” in my Shiraz or Chardonnay. What is the solution to this problem?

Winemakers use a fining agent to flocculate at various stages during wine production, ensuring your Hunter Valley Semillon is crystal clear. Clarity, brightness and transparency are important for both the wine judge, and us wine drinkers.

Flocculation: [verb] forced removal of sediment from a liquid through addition of a flocculating agent. Gravity controlled flocculation precipitates solids within a liquid.

Now for the science lesson: as the diagram suggests, the fining agent is added to the top of the tank, weighs down on the dead yeast cells (and other “floaties”) and drags everything to the bottom of the tank where it can be siphoned off.

Fining agents can improve haze, phenolics, astringency, colour, flavour and even off-odour in wine. Therefore, fining is a process which results in a wine created with finesse, which may also have attractive qualities not present in unfined wine.

Stabilisation can be used to prevent wine faults caused by environmental changes to temperature, humidity and movement. Unstable wines can be subject to haze, tartrates and premature ageing. For example, Cold stabilisation encourages liquid tartaric acid to solidify. “Wine Diamonds” (tartrate crystals) form when the wine is very cold. They develop in small crystals or long shards and can be removed prior to bottling. Sometimes these form in the finished bottle – they may look like glass but are completely harmless.

So where does fish come into this? Not to worry – winemakers are certainly not throwing seafood medley into the tank!

Below are some common fining agents:

Isinglass (pronounced eye-sin-glass) is a gelatin derived from the air bladder of a fish – especially and traditionally the sturgeon. Isinglass is expensive, delicate, will not strip flavour and often used with white wines.

Gelatin has been used to fine wine since Roman civilisation. It can remove harsh tannins, bitter flavours, and improve astringency.

Casein. Casein is an active protein in skim milk or powdered skim milk. It can be used to nullify astringency and bitterness in white wines, sometimes lightening the colour.

PVPP or polyvinyl-polypyrrolidone is a synthetic polymer chain that behaves like a natural protein.

Albumin is the fining agent relating to eggs. Only the whites are used (sometimes powdered) – so never sunny side up! This is usually reserved for red wines and believe it or not it’s only 1-2 egg whites for 100 Litres of wine.

There are natural proteins present in grapes that may cause a cloudy haze if the wine is subject to higher temperatures. Bentonite is a naturally occurring clay or mineral derivative that stabilises the wine, preventing cloudy protein haze in the wine.

Did you know? Bulls blood was commonly used as a fining agent in many European countries including France, until 1997 when the EU banned this practice as a measure to curb Mad Cow’s Disease.

If I’m allergic to seafood do I have to avoid wine?

No. Not even with wines fined with Isinglass. The protein in fish which commonly causes allergic reactions is called parvalbumin. It’s not normally found in isinglass.

Modern manufacture of isinglass ensures no residual parvalbumin remains. The European Food Safety Commission led the way and granted isinglass exemption from allergen labelling laws. In 2009, Food Standards Australia New Zealand (FSANZ) also granted food labelling exemption for isinglass in beer and wine. Even if trace parvalbumin snuck into the wine with the isinglass, it would settle with the isinglass when flocculated and be removed in the filtration process.

This doesn’t sound kosher!

Well technically, isinglass that is derived from a sturgeon isn’t. However isinglass from a kosher fish is. Other un-kosher fining agents include gelatin, casein.

I’m a vegetarian /vegan?

A lot of wines on the market are still unfined or use vegetarian-friendly fining agents. Synthetic fining agents are increasingly popular, and Bentonite is one of the most common fining agents. It is important to consider that some wines and many beers may not be suitable.

Vegans can look for wines that boast “unfined” or “unfiltered” or Bentontite/clay. Some wineries are cleverly labelling for vegetarian and vegan consumption determined by their winemaking processes. Just because some wines are labelled as vegetarian-friendly doesn’t mean that the wines that don’t specify aren’t already suitable for vegetarians or vegans. Continue enjoying Hunter Valley wines and if you are concerned – read the label and ask the friendly folks at the winery.

Testing has shown that there is limited capacity for wines to absorb fining agents and when they have been detected, only in negligent proportions. Fining is considered more natural and delicate a process than filtration which can rapidly strip a wine of colour and flavour. It’s also an important part of traditional winemaking practice that Australian winemakers have inherited from our old world wine countries.

So now you know more about the processes behind some of our proud award winning wines– celebrate quality Hunter Valley wines and appreciate the complexity of the science and skill it took to produce them.

Cheers to that!

 

This article was published in Breathe Magazine – Issue 30, Spring 2011  “Hunter Valley Wine Show edition” – see link.

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I often get asked why there are warnings on wine labels pertaining to fish, milk and egg products? Aren’t the basic ingredients of wine just grapes and yeast?
Well… Yes. However, there are treatments the wine industry use to ‘fine’ or flocculate wine.

Flocculation: [verb] forced removal of sediment from a liquid through addition of a flocculating agent. Gravity controlled flocculation precipitates solids within a liquid.

Still not getting the gist? Ever had a Coopers beer? Did you see the floaties at the bottom? These “floaties” are dead yeast cells left over from Fermentation. This is  the norm. Think back to the death of yeast man.
This happens in wine too- but no one likes “floaties” in their champagne, chardy or verdelho do they? It’s just not on.

So we use a flocculating agent at various stages during wine production to ensure your Sauvignon Blanc is crystal clear. Clarity is important.

So as the below diagram suggests, the fining agent is added to the top of the tank, weighs down on the dead yeast cells (and other floaties) and drags everything to the bottom of the tank where it can be siphoned off. (I drew this on my iPad!)

20110526-070913.jpg

 

So where does the fish come into this?

Traditional fining agents have followed through from old world wine countries to new world wine countries. Such things as isinglass, milk and eggs are commonly used to clarify wine. They can also be used to improve haze, astringency, colour, flavour and even off-odour.

<<< Rewind <<<
Isinglass: [noun] A gelatin derived from the air bladder of a fish – especially and traditionally the sturgeon.

Isinglass is expensive, delicate and will not strip flavour – often used with white wines.

Other Fining agents include:

- eggs: whites only – never sunny side up! Also known as albumin. Usually reserved for red wines and believe it or not it’s only 1-2 egg whites for 100 litres of wine. Barn laid or free range?
-milk: casein, a protein in milk is responsible and wineries usually go for skim milk or powdered skim milk. Often used on white wines.
-chitin: a shellfish bi-product
-bentonite: a clay derivative that is used on white wines and prevents cloudy protein haze.
-blood: in mediterranean countries they have used bulls blood. Well… Twilight made this popular again right?

Hold on? If I’m allergic to seafood do I have to avoid wine?

No. The protein in fish which commonly causes allergic reactions is called parvalbumin. It’s not normally found in isinglass. By the way, modern manufacture of isinglass ensures no residual parvalbumin remains. The European Food Safety Commission led the way and granted isinglass exemption from allergen labelling laws. In 2009, Food Standards Australia New Zealand (FSANZ) also granted food labeling exemption for isinglass in beer and wine.
Even if trace parvalbumin snuck into the wine with the isinglass, it would settle with the isinglass when flocculated and be removed in the filtration process.

Hold on? This doesn’t sound kosher!

Well technically, isinglass that is derived from a sturgeon isn’t. However isinglass from a kosher fish is. Other un-kosher fining agents include gelatin, casein.

Hold on? I’m a vegetarian /vegan?

If you’re a vegetarian that eats eggs and milk than you’re still in luck. If not, many wines and beers including Guiness are not suitable. Look for wines labelled V for vegan or those that indicate bentonite/ clay/ earth finings.
You can also look for wines that boast “unfined” or “unfiltered”. However it’s good to remember- if it lived on the bunch, it went into the bucket, which went into the bin, which went into the crusher, which was pressed and fermented.

If you’re a vegetarian that eats milk, eggs, vinegar flies, bugs and spiders then I’m sure it’s okay! Oh and we never found the end of that guys finger in 1999 – so if you find it please do let us know….
Between you and me, I prefer my wine bugs to be clarified. Anyway, tests show that there is limited capacity for these wines to absorb these fining agents. We just have to tell you about them is all. Its all in the disclosure.

Some wines will self stabilise- meaning eventually they will sort out their own problems. But if I can’t self-stabilise then how can I expect my chardonnay to? That’s why I needed a Chardonnay in the first place!

And it’s not just wine and beer. Ever wonder why apple juice when juiced at home is opaque and apple juice from the supermarket bought bottle is clear? They also use gelatin or bentonite to flocculate. The particles which make it cloudy precipitate to the bottom of the tank – just like in wine- and are drained off.

So please, continue enjoying your wine and if you are concerned – read the label, ask the winery – but ultimately the main ingredients are grapes and yeast and oak if you are lucky! Eggs, milk, bentonite, isinglass (and perhaps bugs) only visit for a brief stay. And just like your in-laws, they never move in permanently!

Happy International Chardonnay Day!

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